Discovery challenges accepted rule of organic solar cell design

phys.org | 8/14/2019 | Staff
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Solar cells that use mixtures of organic molecules to absorb sunlight and convert it to electricity, that can be applied to curved surfaces such as the body of a car, could be a step closer thanks to a discovery that challenges conventional thinking about one of the key components of these devices.

A basic organic solar cell consists of a thin film of organic semiconductors sandwiched between two electrodes which extract charges generated in the organic semiconductor layer to the external circuit. It has long been assumed that 100% of the surface of each electrode should be electrically conductive to maximise the efficiency of charge extraction.

Scientists - University - Warwick - Electrodes - Cells

Scientists at the University of Warwick have discovered that the electrodes in organic solar cells actually only need 1% of their surface area to be electrically conductive to be fully effective, which opens the door to using a range of composite materials at the interface between the electrodes and the light harvesting organic semiconductor layers to improve device performance and reduce cost. The discovery, published today (11 September), is reported in Advanced Functional Materials.

The academic lead, Dr. Ross Hatton from the University's Department of Chemistry, said: "It's widely assumed that if you want to optimise the performance of organic solar cells you need to maximize the area of the interface between the electrodes and the organic semiconductors. We asked whether that was really true."

Researchers - Model - Electrode - Surface - Area

The researchers developed a model electrode that they could systematically change the surface area of, and found that when as much as 99% of its surface was electrically insulating the electrode still performs as well as if 100% of the surface was conducting, provided the conducting regions aren't too far apart.

High performance organic solar cells have additional transparent layers at the interfaces between the electrodes and the light harvesting organic semiconductor layer that...
(Excerpt) Read more at: phys.org
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